Scientific Works

ISSN-print: 2073-8730
ISSN-online:
ISO: 26324:2012
Archives

THERMAL ANALYSIS OF BIOMASS OF CHLOROPHYLL SYNTHESIZED MICROALGAE CHLORELLA VULGARIS

##plugins.themes.bootstrap3.article.main##

Василь Володимирович Дячок
https://orcid.org/0000-0002-5376-5256
Вікторія Віталіївна Кочубей
https://orcid.org/0000-0003-1537-3953

Abstract

The paper presents ways to reduce the carbon footprint through the reuse of microalgae biomass as biofuel (related to bio-CCU). Processing of microalgae biomass into biochar is used for carbon sequestration, raw material for the production of thermal energy, as well as activated carbon and adsorption of toxic compounds from polluted air, water and soil. Biofuels are considered carbon neutral because the CO2 released after they are burned is used by plants and algae for photosynthesis, which leads to carbon dioxide fixation. Obtaining energy by burning carbonized biomass of microalgae is based on the effect of carbon dioxide neutralization, which significantly distinguishes this method from known traditional methods, and does not cause environmental pollution with greenhouse gases. The results of complex thermogravimetric and differential thermal analyzes of the calorific value of biochar based on the biomass of chlorophyll-synthesizing microalgae Chlorella vulgaris obtained as a result of the sorption of greenhouse gases formed during the burning of solid, liquid or gaseous fuels.It was established that the biomass of microalgae obtained by absorbing carbon dioxide, a product of fuel combustion with sulfur dioxide impurities, has a greater heat-generating capacity compared to the biomass obtained by absorbing pure carbon dioxide. Combustion of microalgae biomass, which contains sulfur compounds in the internal volume of cells, which are formed as a result of the metabolism of sulfur dioxide, is accompanied by more significant exothermic effects. According to the results of thermal studies, it was established that the heat-generating capacity of such microalgae biomass exceeds the heat-generating capacity of aspen (Populus tremula), which is an alternative source of energy in the territory of Ukraine, and is close to the heat-generating capacity of the selectively bred energetic willow (Salix Viminalis).

Keywords:
thermogravimetric analysеs, differential thermal analysеs, microalgae Chlorella vulgaris, greenhouse gases, alternative fuel

##plugins.themes.bootstrap3.article.details##

How to Cite
Дячок, В., & Кочубей, В. (2023). THERMAL ANALYSIS OF BIOMASS OF CHLOROPHYLL SYNTHESIZED MICROALGAE CHLORELLA VULGARIS. Scientific Works, 87(1), 43-49. https://doi.org/10.15673/swonaft.v87i1.2689
Section
Статті

References

1. Vasylyshyn R.D. (2013). Energetics of forest ecosystems: main directions and trends of scientific research. Scientific bulletin of NLTU of Ukraine: coll. science and technology works –Lviv: RVV NLTU of Ukraine. 23(2), 31-36.
2. Lakyda P.I., Vasylyshyn R.D., Lashchenko A.G., Terentiev A.Yu and oll. Species of Ukraine: reference book (normative and production edition): ECO-inform, 192.
3. Geletukha H.G., Zhelezna T.A. (2012). Current state and prospects for the development of bioenergy in Ukraine. Non-traditional energy. Prom. Heat engineering. 3,73-79.
4. Ivakhiv V. (2012). Energy willow as a solution for small cities of Ukraine. Ukrainian energy industry. 12.
5. Climate change (in Ukrainian), (2020). Natsionalnyy ekolohichnyy tsentr Ukrainy. Retrieved from: necu. org.ua/climate.
6. María J.Lapponi, Mariana B.Méndez, Jorge A.Trelles, Cintia W.Rivero (2022). Cell immobilization strategies for biotransformations. Current Opinion in Green and Sustainable Chemistry, 33.
7. Manswama Boro, Ashwani Kumar Verma, Dixita Chettri, Vinod KumarYata, Anil Kumar Verma (2022). Strategies involved in biofuel production from agro-based lignocellulose biomass. Environmental Technology; Innovation, 28.
8. Yi An Lim, Meng Nan Chong, Su Chern Foo, I.M.S.K. (2021). Ilankoon. Analysis of direct and indirect quantification methods of CO2 fixation via microalgae cultivation in photobioreactors: A critical review . Renewable and Sustainable Energy Reviews.137.
9. Harun Chowdhury (2019). Third-generation biofuels from microalgae: a review Current Opinion in Green and Sustainable Chemistry. 20, 39-44.
10. Dyachok V., Huhlych S., Katysheva V.V., Mandryk S.T. (2021). About the Optimal Ratio Inhibitor and Activators of Carbon Dioxide Sorption Process by Using Chlorophyll-synthesizing Chlorella microalgae Journal of Ecological Engineering , 22(5), 26–31
11. Dyachok V., Huhlych S., Katysheva V.V., Mandryk S.T. (2017). Absorption of carbon dioxide from a mixture of air with sulfur dioxide Scientific works, 81(1), 59-65. (in Ukrainian).
12. Dyachok V.V., Mandryk S.T., Huhlych S.I., Slyvka M.M. (2020). Study on the impact of activators in the presence of an inhibitor on the dynamics of carbon dioxide absorption by chlorophyll-synthesizing microalgae. Journal of Ecological Engineering, 21(5), 189-196.
13. Chlorella in sewage treatment, (2020). Retrieved from: https://hlorella.jimdo.com/. (in Ukrainian)
14. Zolotaryova O.K., Shnyukova Ye.I., Syvash O.O., Mykhaylenko N.F. (2008). Prospects for the use of micro-algae in biotechnology. In: O.K. Zolotaryovoa (Ed.) Alterpres, 234. (in Ukrainian)
15. Yalechko V., Kochubey V, Hnatyshyn Y., Dzyadevych B. and. Zaikov G. (2015). Investigation of Thermal Power Characteristics of Wood Pulp. The Chemistry and Physics of Engineering Materials – Two Volume Set.: Modern Analytical Methodologies. Apple Academic Press, USA. 1, 171–178.
16. Tsapko Y.V. (2011).The study of kinetic parameters during pyrolysis of fire protected wood by impregnating agents. Fire safety, 19, 163 - 169.