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Анотація
The article deals with ecological safety, resource saving, economic efficienty in the technologies of wastewater purification from heavy metals ions. It is shown that modern technologies of wastewater purification from such substances need to be improved. А promising way to solve this problem is the production and wide use of carbon sorbents obtained from the waste of processing agricultural raw materials and waste generated at food enterprises. Scientific research is actively carried out in this area. This is due to the possibility of organizing the process of wastewater purification from heavy metal ions in a cheap and effective way. The development of biosorbent production is relevant for Ukraine, as the development of agriculture and food industry is of primary importance. The article presents the results of an analytical review of literary sources on various aspects of the scientific problem. In particular, possible sources of raw materials for the production of biosorbents, classical and modified technologies for their production, mechanisms of biosorption using raw materials with different chemical composition, sorption characteristics of biosorbents, and indicators of the economic efficiency of their production are considered.
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Як цитувати
KovalenkoО., Novoseltseva, V., & Kovalenko, N. (2018). BIOSORBENTS – PROSPECTIVE MATERIALS FOR HEAVY METAL IONS EXTRACTION FROM WASTEWATER. Food Science and Technology, 12(1). https://doi.org/10.15673/fst.v12i1.841
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Розділ
Технологія і безпека продуктів харчування
Посилання
1. Wan Ngah, WS. Removal of heavy metal ions from wastewater by chemically modified plant wastes as adsorbents: Bioresource Technology. 2008 Aug. 99. 3935–3948. https://doi.org/10.1016/j.biortech.2007.06.011
2. Shmandiy VM, Bezdenezhnykh LA, Kharlamova EV. Use of adsorbents derived from waste to improve the state of the human environment: Hygiene and Sanitation. 2012. 6. 44 - 45.
3. Mohan D, Singh KP, Singh VK. Wastewater treatment using low cost activated carbons derived from agricultural byproducts - A case study: Journal of hazardous materials. 2008. 3(152). 1045 – 1053. https://doi.org/10.1016/j.jhazmat.2007.07.079
4. Yamansarova ET, Khasanova DN, Abdullin MI, Gromyko NV. Economic aspects of the application of sorbents on the basis of agricultural wastes for the purification of natural waters from oil and products based on it: Scientific journal NI UITMO. - Series: Economics and Environmental Management. - 1, 2016. 118 -122.
5. Tsertsvadze LA, Dzadzamaniya TD, Petriashvili ShG, Chutkerashvili DG, Kirkesali EI, Frontasyaeva MV, Pavlov SS, Gundorina SF. Biosorption of metals from multicomponent bacterial solutions: Preprint of the Joint Institute for Nuclear Research, Dubna. 2002. 14.
6. Serpokrylov NS, Borisova VYu, Hamel A, Kondakova NV. Modification of rice straw for the purpose of obtaining a sorption material for cleaning aqueous media from ammonium ions: Engineering and construction bulletin of the Caspian Sea: scientific and technical journal / Astrakhan State University of Architecture and Civil Engineering. Astrakhan, 2016, 4 (18). 53-56.
7. Nowicki P, Pietrzak R, Wachowska H. Sorption properties of active carbons obtained from walnut shells by chemical and physical activa-tion: Catalysis Today. 2010. 1(152).107 – 114. https://doi.org/10.1016/j.cattod.2009.11.009
8. Junior, OK, Gurgel, LVA, de Melo, JCP, Botaro, VR, Melo, TMS. Adsorption of heavy metal ion from aqueous single metal solution by chemically modified sugarcane bagasse: Bioresour. Technol. 2006. 98. 1291–1297. https://doi.org/10.1016/j.biortech.2006.05.013
9. Nasernejad, B, Zadeh, TE, Pour, BB, Bygi, ME, Zamani, A. Comparison for biosorption modeling of heavy metals (Cr(III), Cu(II), Zn(II)) adsorption from wastewater by carrot residues: Process Biochem. 2005. 40. 1319–1322. https://dx.doi.org /10.4236/jep.2014.54032
10. Pehlivan, E, Cetin, S, Yanık, BH. Equilibrium studies for the sorption of zinc and copper from aqueous solutions using sugar beet pulp and fly ash: J. Hazard. Mater. 2006. 135. 193–199. https://doi.org/10.1016/j.jhazmat.2005.11.049
11. Sionikhina, AN. Sorption of heavy metal ions from aqueous solutions with a cellulose-containing sorbent modified with polyvinylpyrrolidone. Sionikhina, ТЕ. Nikiforova: Fundamental research. 2011. 12. 773-776.
12. Wong, KK. Removal of Cu and Pb by tartaric acid modified rice husk from aqueous solutions: Chemosphere. 2003. 50. 23–28. https://doi.org/10.1016/S0045-6535(02)00598-2
13. Sheveleva IV, Holomeydik AN, Voit AV, Zemnukhova LA Sorbents based on rice husk to remove Fe (III), Cu (II), Cd (II), Pb (II) ions from solutions: Chemistry of Plant Raw Materials. 2009. 4. 171 - 176.
14. Zhashueva KA, Sivolobov NO, Gracheva NV, Sikarska AV. Purification of water from ions of heavy metals by adsorbents on the basis of vegetable raw materials: Bulletin of the Technological University. 2017.7(20). 142 - 143.
15. Patent 2329098 RU. Method for extraction of heavy metal ions from aqueous solutions / ТЕ Nikiforova, VA Kozlov, MV Rodionov. Published 07/20/2008.
16. Annadurai, G, Juang, HS, Lee, DJ, Adsorption of heavy metal from water using banana and orange peels: Water Sci. Technol. 2002. 47. 185–190.
17. Modrzejewskaa, Z. Sorption of copper by chitosan hydrogel: Kinetics and equilibrium / Z Modrzejewskaa, G Rogackia, W Sujkaa, R Zarzyckib: Chemical Engineering and Processing: Process Intensification. 2016. 109. 104-113. https://doi.org/10.1016/j.cep.2016.08.014
18. Guo, M. Poultry litter-based activated carbon for removing heavy metal ions in water / M Guo, G Qiu, W Song: Waste Management. 2010. 30. 308–315. https://doi.org/10.1016/j.wasman.2009.08.010
19. Jaramillo, J. Enhanced adsorption of metal ions onto functionalized granular activated carbons prepared from cherry stones / J Jaramillo, V Gomez-Serrano, PM Alvarez: Journal of Hazardous Materials. 2009. 161. 670-676. https://doi.org/10.1016/j.jhazmat.2008.04.009
20. Patent No. 2299948. Method for producing oxidized coal from plant raw materials for wastewater treatment from copper ions / LN Adeeva, MV Odintsov. - Published. 27.07.2008.
21. Milenkovic, DD. Ultrasound- assisted adsorption of copper (II) ions on haselnut shell activated carbon / DD Milenkovic, PV Dasic, VB Veljkovich: Ultrasonics Sonochemistry. 2009. 4(16). 557-563. https://doi.org/10.1016/j.ultsonch.2008.12.002
22. Shukla, SR, Pai, RS. Adsorption of Cu(II), Ni(II) and Zn(II) on dye loaded groundnut shells and sawdust: Sep. Purif. Technol.2005. 43. 1–8. https://doi.org/10.1016/j.seppur.2004.09.003
23. Chubar, N, Calvalho, JR, Correia, MJN. Heavy metals biosorption on cork biomass: effect of the pre-treatment: Colloids Surf. 2004. 238. 51–58. https://doi.org/10.1016/j.colsurfa.2004.01.039
24. Çay, S. Single and binary component adsorption of copper (II) and cadmium (II) from aqueous solutions using tea-industry waste: Separa-tion and Purification Technology. 2004. 38. 273–280. https://doi.org/10.1016/j.seppur.2003.12.003
25. Glinina, EG. Use of plant raw materials for purification of industrial wastewater from copper ions: Natural sciences. 2009. 4. 172-175.
26. Li Q, Zhai J, Zhang W. A study on sorption of Pb(II), Cr(II) and Cu(II) from aqueous solution by peanut husk // Bulletin of the chemical society of Ethiopia. 2008. 1(22). 19 – 26. https://doi.org/10.1016/j.jhazmat.2006.06.109
27. Zemnukhova LA, Shkorina ED, Fedorischeva GA. Investigation of inorganic components of buckwheat and buckwheat straw: Journal of Applied Chemistry. 2005. 2(78). 329 - 333.
28. Dastheib SA, Rokstraw DA. A model for the adsorption of single metal ion solutes in aqueous solution onto activated carbon produced from pecan shells: Carbon, 2002. 11(40). 1843 – 1851. https://doi.org/10.1016/S0008-6223(02)00037-4
29. Pehlivan E, Altun T, Cetin S. Lead sorption by waste biomass of hazelnut and almond shell: Journal of hazardous materials, 2009. 1-3(167). 1203 – 1208. https://doi.org/10.1016/j.jhazmat.2009.01.126
30. A new directory of chemist and technologist. Processes and equipment of chemical technologies. Part.II. - St. Petersburg: Scientific and Production Association "Professional". 2006. 916 ISBN 5-91259-003-8
2. Shmandiy VM, Bezdenezhnykh LA, Kharlamova EV. Use of adsorbents derived from waste to improve the state of the human environment: Hygiene and Sanitation. 2012. 6. 44 - 45.
3. Mohan D, Singh KP, Singh VK. Wastewater treatment using low cost activated carbons derived from agricultural byproducts - A case study: Journal of hazardous materials. 2008. 3(152). 1045 – 1053. https://doi.org/10.1016/j.jhazmat.2007.07.079
4. Yamansarova ET, Khasanova DN, Abdullin MI, Gromyko NV. Economic aspects of the application of sorbents on the basis of agricultural wastes for the purification of natural waters from oil and products based on it: Scientific journal NI UITMO. - Series: Economics and Environmental Management. - 1, 2016. 118 -122.
5. Tsertsvadze LA, Dzadzamaniya TD, Petriashvili ShG, Chutkerashvili DG, Kirkesali EI, Frontasyaeva MV, Pavlov SS, Gundorina SF. Biosorption of metals from multicomponent bacterial solutions: Preprint of the Joint Institute for Nuclear Research, Dubna. 2002. 14.
6. Serpokrylov NS, Borisova VYu, Hamel A, Kondakova NV. Modification of rice straw for the purpose of obtaining a sorption material for cleaning aqueous media from ammonium ions: Engineering and construction bulletin of the Caspian Sea: scientific and technical journal / Astrakhan State University of Architecture and Civil Engineering. Astrakhan, 2016, 4 (18). 53-56.
7. Nowicki P, Pietrzak R, Wachowska H. Sorption properties of active carbons obtained from walnut shells by chemical and physical activa-tion: Catalysis Today. 2010. 1(152).107 – 114. https://doi.org/10.1016/j.cattod.2009.11.009
8. Junior, OK, Gurgel, LVA, de Melo, JCP, Botaro, VR, Melo, TMS. Adsorption of heavy metal ion from aqueous single metal solution by chemically modified sugarcane bagasse: Bioresour. Technol. 2006. 98. 1291–1297. https://doi.org/10.1016/j.biortech.2006.05.013
9. Nasernejad, B, Zadeh, TE, Pour, BB, Bygi, ME, Zamani, A. Comparison for biosorption modeling of heavy metals (Cr(III), Cu(II), Zn(II)) adsorption from wastewater by carrot residues: Process Biochem. 2005. 40. 1319–1322. https://dx.doi.org /10.4236/jep.2014.54032
10. Pehlivan, E, Cetin, S, Yanık, BH. Equilibrium studies for the sorption of zinc and copper from aqueous solutions using sugar beet pulp and fly ash: J. Hazard. Mater. 2006. 135. 193–199. https://doi.org/10.1016/j.jhazmat.2005.11.049
11. Sionikhina, AN. Sorption of heavy metal ions from aqueous solutions with a cellulose-containing sorbent modified with polyvinylpyrrolidone. Sionikhina, ТЕ. Nikiforova: Fundamental research. 2011. 12. 773-776.
12. Wong, KK. Removal of Cu and Pb by tartaric acid modified rice husk from aqueous solutions: Chemosphere. 2003. 50. 23–28. https://doi.org/10.1016/S0045-6535(02)00598-2
13. Sheveleva IV, Holomeydik AN, Voit AV, Zemnukhova LA Sorbents based on rice husk to remove Fe (III), Cu (II), Cd (II), Pb (II) ions from solutions: Chemistry of Plant Raw Materials. 2009. 4. 171 - 176.
14. Zhashueva KA, Sivolobov NO, Gracheva NV, Sikarska AV. Purification of water from ions of heavy metals by adsorbents on the basis of vegetable raw materials: Bulletin of the Technological University. 2017.7(20). 142 - 143.
15. Patent 2329098 RU. Method for extraction of heavy metal ions from aqueous solutions / ТЕ Nikiforova, VA Kozlov, MV Rodionov. Published 07/20/2008.
16. Annadurai, G, Juang, HS, Lee, DJ, Adsorption of heavy metal from water using banana and orange peels: Water Sci. Technol. 2002. 47. 185–190.
17. Modrzejewskaa, Z. Sorption of copper by chitosan hydrogel: Kinetics and equilibrium / Z Modrzejewskaa, G Rogackia, W Sujkaa, R Zarzyckib: Chemical Engineering and Processing: Process Intensification. 2016. 109. 104-113. https://doi.org/10.1016/j.cep.2016.08.014
18. Guo, M. Poultry litter-based activated carbon for removing heavy metal ions in water / M Guo, G Qiu, W Song: Waste Management. 2010. 30. 308–315. https://doi.org/10.1016/j.wasman.2009.08.010
19. Jaramillo, J. Enhanced adsorption of metal ions onto functionalized granular activated carbons prepared from cherry stones / J Jaramillo, V Gomez-Serrano, PM Alvarez: Journal of Hazardous Materials. 2009. 161. 670-676. https://doi.org/10.1016/j.jhazmat.2008.04.009
20. Patent No. 2299948. Method for producing oxidized coal from plant raw materials for wastewater treatment from copper ions / LN Adeeva, MV Odintsov. - Published. 27.07.2008.
21. Milenkovic, DD. Ultrasound- assisted adsorption of copper (II) ions on haselnut shell activated carbon / DD Milenkovic, PV Dasic, VB Veljkovich: Ultrasonics Sonochemistry. 2009. 4(16). 557-563. https://doi.org/10.1016/j.ultsonch.2008.12.002
22. Shukla, SR, Pai, RS. Adsorption of Cu(II), Ni(II) and Zn(II) on dye loaded groundnut shells and sawdust: Sep. Purif. Technol.2005. 43. 1–8. https://doi.org/10.1016/j.seppur.2004.09.003
23. Chubar, N, Calvalho, JR, Correia, MJN. Heavy metals biosorption on cork biomass: effect of the pre-treatment: Colloids Surf. 2004. 238. 51–58. https://doi.org/10.1016/j.colsurfa.2004.01.039
24. Çay, S. Single and binary component adsorption of copper (II) and cadmium (II) from aqueous solutions using tea-industry waste: Separa-tion and Purification Technology. 2004. 38. 273–280. https://doi.org/10.1016/j.seppur.2003.12.003
25. Glinina, EG. Use of plant raw materials for purification of industrial wastewater from copper ions: Natural sciences. 2009. 4. 172-175.
26. Li Q, Zhai J, Zhang W. A study on sorption of Pb(II), Cr(II) and Cu(II) from aqueous solution by peanut husk // Bulletin of the chemical society of Ethiopia. 2008. 1(22). 19 – 26. https://doi.org/10.1016/j.jhazmat.2006.06.109
27. Zemnukhova LA, Shkorina ED, Fedorischeva GA. Investigation of inorganic components of buckwheat and buckwheat straw: Journal of Applied Chemistry. 2005. 2(78). 329 - 333.
28. Dastheib SA, Rokstraw DA. A model for the adsorption of single metal ion solutes in aqueous solution onto activated carbon produced from pecan shells: Carbon, 2002. 11(40). 1843 – 1851. https://doi.org/10.1016/S0008-6223(02)00037-4
29. Pehlivan E, Altun T, Cetin S. Lead sorption by waste biomass of hazelnut and almond shell: Journal of hazardous materials, 2009. 1-3(167). 1203 – 1208. https://doi.org/10.1016/j.jhazmat.2009.01.126
30. A new directory of chemist and technologist. Processes and equipment of chemical technologies. Part.II. - St. Petersburg: Scientific and Production Association "Professional". 2006. 916 ISBN 5-91259-003-8